1,4-hydrogenation of dienes with Ru complexes

Details 1,4-hydrogenation of dienes with Ru complexes 1,4-hydrogenation of dienes with Ru complexes

2011-08-23

2011-08-23

Gonzalez, Porfirio Nazario (Department: 1621)

Chemistry of hydrocarbon compounds

Adding hydrogen to unsaturated bond of hydrocarbon, i.e.,...

By hydrogen transfer from other hydrocarbon

C568S687000, C568S903000, C556S136000

Reexamination Certificate

active

08003838

ABSTRACT:
The present invention relates to the use of Ruthenium complexes having cyclopentadienyl derivatives and a diene as ligands, together with some acidic additives for improving the selectivity in the 1,4-hydrogenation of conjugated dienes into the corresponding “cis”-alkene as major product, i.e. wherein the two substituents in position 2,3 of the diene are in a cis configuration in the corresponding alkene.

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