1,2,3,4,5,6-He xahydro-3-(3-methyl-2-butenyl)-6-methyl-11(EQ)-hy

Details 1,2,3,4,5,6-He xahydro-3-(3-methyl-2-butenyl)-6-methyl-11(EQ)-hy 1,2,3,4,5,6-He xahydro-3-(3-methyl-2-butenyl)-6-methyl-11(EQ)-hy

1975-03-06

1979-04-10

Trousof, Natalie

Organic compounds -- part of the class 532-570 series

Organic compounds

Heterocyclic carbon compounds containing a hetero ring...

424267, C07D22126

Patent

active

041490002

ABSTRACT:
11-Oxygenated-2,6-methano-3-benzazocines N-alkylated by alkylmethyl, haloalkenylmethyl, alkynylmethyl, cycloalkylmethyl, cycloalkenylmethyl, cycloalkyl or 2-cycloalkenyl are prepared directly by N-alkylation of the corresponding N-H intermediates or indirectly by N-acylation of the corresponding N-H intermediates followed by reduction of the resulting N-acylated intermediates and are useful as antagonists of narcotic analgesics.

REFERENCES:
patent: 3639407 (1972-02-01), Clarke et al.
patent: 3700734 (1972-10-01), Robinson et al.
patent: 3891657 (1975-06-01), Monkovic et al.
Saito et al., J. Org. Chem. 26, pp. 4536-4540 (1961).

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