Silver halide photographic material

Radiation imagery chemistry: process – composition – or product th – Radiation sensitive product – Silver compound sensitizer containing

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430579, 430592, G03C 110, G03C 126

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active

060542594

ABSTRACT:
A silver halide photographic material which contains at least one methine compound represented by the following formula (I) or (II): wherein Z.sub.1, Z.sub.2 and Z.sub.3 each represents an atomic group necessary to form a 5- or 6-membered nitrogen-containing heterocyclic ring; R.sub.1 and R.sub.3 each represents an alkyl group; R.sub.2 represents a hydrogen atom, an alkyl group, an aryl group or a heterocyclic group; L.sub.1, L.sub.2, L.sub.3, L.sub.4, L.sub.5, L.sub.6, L.sub.7, L.sub.8 and L.sub.9 each represents a methine group; p.sub.1 and p.sub.2 each represents 0 or 1; n.sub.1 and n.sub.2 each represents 0, 1, 2, 3 or 4; M.sub.1 represents a counter ion to balance a charge; and m.sub.1 represents a number of 0 or more necessary for to neutralize a charge in the molecule; provided that at least one of R.sub.1, R.sub.2, R.sub.3, Z.sub.1, Z.sub.2, Z.sub.3, L.sub.1, L.sub.2, L.sub.3, L.sub.4, L.sub.5, L.sub.6, L.sub.7, L.sub.8 and L.sub.9 has a thioether group; ##STR1## wherein Z.sub.4, Z.sub.5 and Z.sub.6 each represents an atomic group necessary to form a 5- or 6-membered nitrogen-containing heterocyclic ring; R.sub.4 represents an alkyl group; R.sub.5 and R.sub.6 each represents a hydrogen atom, an alkyl group, an aryl group or a heterocyclic group; L.sub.10, L.sub.11, L.sub.12, L.sub.13, L.sub.14 and L.sub.15 each represents a methine group; p.sub.3 represents 0 or 1; n.sub.3 and n.sub.4 each represents 0, 1, 2, 3 or 4; M.sub.2 represents a counter ion to balance a charge; and m.sub.2 represents a number of 0 or more necessary for to neutralize a charge in the molecule; provided that at least one of R.sub.4, R.sub.5, R.sub.6, Z.sub.4, Z.sub.5, Z.sub.6, L.sub.10, L.sub.11, L.sub.12, L.sub.13, L.sub.14 and L.sub.15 has a thioether group.

REFERENCES:
patent: 3706570 (1972-12-01), Nakazawa et al.
patent: 3971664 (1976-07-01), Nakazawa et al.
patent: 5112731 (1992-05-01), Miyasaka
patent: 5457022 (1995-10-01), Hioki et al.
patent: 5587279 (1996-12-01), Mifune et al.
patent: 5763153 (1998-06-01), Tsuzuki et al.

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