Fluoroelastomers endowed with improved processability and proces

Details Fluoroelastomers endowed with improved processability and proces Fluoroelastomers endowed with improved processability and proces

1990-07-09

1992-12-22

Schofer, Joseph L.

Synthetic resins or natural rubbers -- part of the class 520 ser

Synthetic resins

Polymers from only ethylenic monomers or processes of...

526255, 526254, 526247, C08F 400

Patent

active

051735539

ABSTRACT:
Fluoroelastomers characterized by the presence of iodine or bromine atoms at the end of the polymeric chain in an amount equal to or lower than 1 iodine or bromine atom per polymeric chain, and by a bromine content in the chain ranging from 0.05 to 2% by weight referred to the total weight of the monomeric units.
Said fluoroelastomers exhibit improved characteristics of processability, particularly as regards the utilization in injection molding processes and the detaching from the molds, as well as of stability to heat.
A process for preparing fluoroelastomers containing iodine or bromine atoms at the ends of the polymeric chain, in an amount equal to or lower than 1 iodine or bromine atom per polymeric chain, which process comprises polymerizing mixes of fluorinated monomers (VDF, TFE, HFP, FVE) in bulk, in suspension, in aqueous emulsion, or in solution of organic solvents by means of radical starters, in the presence of compounds capable of providing I.sup.- or Br.sup.- ions in the polymerization medium and conditions.

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