Method for the selective preparation of secondary alcohols and d

Details Method for the selective preparation of secondary alcohols and d Method for the selective preparation of secondary alcohols and d

1982-08-23

1984-07-24

Helfin, Bernard

Chemistry of carbon compounds

Miscellaneous organic carbon compounds

C-metal

568877, 568618, 560247, 260980, 564296, 252351, 252353, 252357, 252DIG1, C07C 6704, C07C 2702, C07C 4103

Patent

active

044617291

ABSTRACT:
A method for preparation of secondary alcohol mixtures by selective reaction of an olefin or olefin mixture and a carboxylic acid compound in the presence of a particular type of shape selective zeolite catalyst. The reaction selectively produces .alpha.-methylalkyl carboxylate enriched ester product which, upon subsequent hydrolysis, yields the desired 2-alcohol enriched secondary alcohol product.

REFERENCES:
patent: 1970578 (1934-08-01), Schoeller et al.
patent: 2671116 (1954-03-01), Kosmin
patent: 3492341 (1970-01-01), Trevillyan
patent: 4251673 (1981-02-01), Mark et al.
patent: 4365083 (1982-12-01), Young
patent: 4365084 (1982-12-01), Young
Brewster, Organic Chemistry, (1948), 228-229.
Morrison et al., Organic Chemistry, 3rd Ed., (1973), 455 and 752.
Schick, Nonionic Surfactants (1967), 384.
Kirk-Othmer Encyclopedia of Chemical Technology, Third Edition, vol. 1, pp. 728-729, (1978), Regarding the Conversion of Alcohols to Surfactants.

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