Preparation of octadienols

Organic compounds -- part of the class 532-570 series – Organic compounds – Oxygen containing

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C07C 2900, C07C 3302

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049622439

ABSTRACT:
Octadienols are prepared by teleomerization of 1,3-butadiene with water in the presence of carbon dioxide and a catalyst system comprising a palladium compound and a tertiary phosphorus compound by performing the reaction in the presence of a strong non-coordinating acid.

REFERENCES:
patent: 3534088 (1970-10-01), Bryant et al.
patent: 3670029 (1972-06-01), Romanelli et al.
Patents Abstracts of Japan, (Kokai No. 53-147013).
F. A. Cotton, et al., Anorganische Chemie, 3rd edition, Verlag Chemie, Interscience Publishers, pp. 179, 238, 394 and 506.
Chem. Abstracts 80, Oct. 20, 1973, 59446C, (Japan, Kokai 73/78,107).

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