Composition and use

Compositions – Absorptive – or bindive – and chemically yieldive

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540455, 252180, C01B 3116

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active

051732106

ABSTRACT:
A composition comprising a chelating compound which is a macrocyclic compound containing at least two coordinating centers in the ring, at least one of which is a neutral base moiety, and an organic acid containing at least one alkyl or alkenyl group containing 8 or more carbon atoms. The macrocyclic compound contains at least 10 ring atoms and especially at least 12 ring atoms. The neutral base moiety is typically a nitrogen moiety. Preferably there are at least four coordinating centers at least two of which are neutral base moities. The acid can be an alkyl or alkenyl substituted acid for example a long chain carboxylic acid. The composition can be used as an extractant system for the selective extraction of metals from an aqueous phase into an organic phase.

REFERENCES:
patent: 4142020 (1979-02-01), Okamura et al.
patent: 4156683 (1979-05-01), Lehn
patent: 4917825 (1990-04-01), McDowell et al.
patent: 4960882 (1990-10-01), Bradshaw et al.
Lindoy "Heavy Metal Chemistry of Mixed Donor Macrocyclic Ligands: Strategies for Obtaining Metal Ion Recognition" Progress in Macrocyclic Chemistry, R. M. Izatt, ed. vol. 3, 99-53-92.
Bartsh et al. "High Lithium Selectivity in Competitive Alkali-Metal Solid Extraction by Lipophyllic Crown Carboxylic Acids" J. A. C. S. 107, 4997-4998 (1985).
Sukhan et al. "Extraction of Copper, Nickel and Cobalt Complexes with Unsaturated Macrocyclic Tetramines and Carboxylic Acids" Ukrainskii Khimicheskii Zhurnal, vol. 49, No. 9, pp. 956-960 (1983).
Morosanova et al. "New Macrocyclic Reagents Containing Nitrogen and Oxygen" Doklady Akademii Nauksssr, Col. 277, No. 5, pp. 1151-1154 Aug. 1984.
Adam et al.; "Ligand Design and Metal-Ion Recognition. Interaction of Nickel(II) with 17- to 19-Membered Macrocycles Containing O.sub.2 N.sub.3 and O.sub.3 N.sub.2 Donor Sets and the X-ray Structure of the Parent 17-Membered Macrocyclic Ligand", J.A.C.S., vol. 105, No. 14, (1983) pp. 4645-4651.
Lindoy et al.; "Metal-Ion Recognition. Interaction of O.sub.2 N.sub.2 -Donor Macrocycles with Cobalt (II), Zince (II), and Cadmium (II) and Structure of the Zinc Complex of One Such 15-Membered Macrocycle", Inorg. Chem., vol. 19, No. 11, (1980) pp. 3360-3365.
Adam et al.; "A New Series of Quinquedentate Macrocycles Exhibiting Systematic Donor-Atom Variation: Equilibrium and X-Ray Structural Data for their Interaction with Copper(II)", J. Chem. Soc., Chem. Commun., No. 14, (1987) pp. 1124-1125.
Chem. Abs. vol. 88, No. 13, (1978) pp. 519, 88:89640w.
Izatt et al.; "Effect of Macrocycle Type on the Extraction into Toluene of Ag.sup.+, Pb.sup.2+, and Cd.sup.2+ Using a Combination of a Macrocycle and Di(2-ethylhexyl)phosphoric Acid as Extractants", Separation Science and Technology, vol. 21, No. 9, (1986) pp. 865-872.
Adam et al.; "Studies Involving Nitrogen-Oxygen Donor Macrocyclic Ligands. Interaction of Copper(II) with New O.sub.2 N.sub.3 -Donor Macrocycles and the X-Ray Analysis of Aqua(1,12,16-triaza-3,4:9,10-dibenzo-5,8-dioxacyclo-octadecane)copper(II) Diperchlorate Hydrate", Journal of the Chemical Society, Dalton Transactions Inorganic Chemistry, (1981) pp. 74-79.
Chemical Abstract 104:140952c, "Synthesis and Characterization of Nickel (II) complexes with Potentially Penadentate Macrocyclic Ligands having N.sub.3 O.sub.2 Donor Sets" Miyokawa et al. Japan 1985.
Chemical Abstract 110:87330u "Metal-Ion Recognition 2, Structural Dislocation Behavior in the Interaction of Zinc (II) and Cadmium (II) with a Series of O.sub.2 N.sub.3 Donor Macrocycles", Adam et al., Australia, 1988.
Chemical Abstract 109:243130r, "Studies on the New Analytical Methods for Separation and Recovery of Rare Earth Metals (I). Adsorption Characteristics of Uranium (VI) Ion by New Synthetic Resins with Macrocyclic Compounds", Jung et al. Korea, 1988.
Chemical Abstract 99:32140f, "Ligand Design and Metal-Ion Recognition. Interaction of Nickel (II) with 17- to 19-Membered Macrocycles Containing O.sub.2 N.sub.3 and O.sub.3 N.sub.2 Donor Sets and the X-ray Structure of the Parent 17-Membered Macrocyclic Ligand" Adam et al. Australia, 1983.

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