Preparation of haloaniline

Chemistry of carbon compounds – Miscellaneous organic carbon compounds – C-metal

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260575, C07C 8500, C07C 8504

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041972597

ABSTRACT:
Haloaniline is produced in high yield by reacting halobenzene with a mixture containing a metal amide and a controlled molar excess of liquid ammonia based on the moles of halobenzene.

REFERENCES:
Wotiz et al, "J. Org. Chem.", vol. 24, pp. 595-598 (1959).
Gilman et al, "J.A.C.S.", vol. 74, pp. 3027-3029 (1952).
Sidgwick, "Organic Chemistry of Nitrogen", p. 143 (1966).
Patai, "The Chemistry of the Amino Group", pp. 58-60 (1968).

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