Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – Polymers from only ethylenic monomers or processes of...
Patent
1998-02-06
2000-09-12
Wu, David W.
Synthetic resins or natural rubbers -- part of the class 520 ser
Synthetic resins
Polymers from only ethylenic monomers or processes of...
526127, 526160, C08F11006
Patent
active
061179620
ABSTRACT:
Stereospecific polypropylene macromers having a high percentage of vinyl terminal bonds and a method for preparing them are provided. The stereospecific polypropylene macromers have number average molecular weights (M.sub.n) of about 2,000 Daltons to about 50,000 Daltons, and the total number of vinyl groups per 1000 carbon atoms is greater than or equal to 7000.div.M.sub.n. The method for preparing the macromers involves:
REFERENCES:
patent: 4530914 (1985-07-01), Ewen et al.
patent: 4542199 (1985-09-01), Kaminsky et al.
patent: 4665208 (1987-05-01), Welborn, Jr. et al.
patent: 4701432 (1987-10-01), Welborn, Jr.
patent: 4769910 (1988-09-01), Noon
patent: 4808561 (1989-02-01), Welborn, Jr.
patent: 4871705 (1989-10-01), Hoel
patent: 4874734 (1989-10-01), Kioka et al.
patent: 4892851 (1990-01-01), Ewen et al.
patent: 4908463 (1990-03-01), Bottelberghe
patent: 4921825 (1990-05-01), Kioka et al.
patent: 4923833 (1990-05-01), Kioka et al.
patent: 4924018 (1990-05-01), Bottelberghe
patent: 4933403 (1990-06-01), Kaminsky et al.
patent: 4937299 (1990-06-01), Ewen et al.
patent: 4952540 (1990-08-01), Kioka et al.
patent: 4968827 (1990-11-01), Davis
patent: 5017714 (1991-05-01), Welborn, Jr.
patent: 5026798 (1991-06-01), Canich
patent: 5057475 (1991-10-01), Canich et al.
patent: 5091352 (1992-02-01), Kioka et al.
patent: 5103031 (1992-04-01), Smith, Jr.
patent: 5120867 (1992-06-01), Welborn, Jr.
patent: 5132381 (1992-07-01), Winter et al.
patent: 5155080 (1992-10-01), Elder et al.
patent: 5157137 (1992-10-01), Sangokoya
patent: 5204419 (1993-04-01), Tsutsui et al.
patent: 5206199 (1993-04-01), Kioka et al.
patent: 5235081 (1993-08-01), Sangokoya
patent: 5240894 (1993-08-01), Burkhardt et al.
patent: 5248801 (1993-09-01), Sangokoya
patent: 5278119 (1994-01-01), Turner et al.
patent: 5278264 (1994-01-01), Spaleck et al.
patent: 5296434 (1994-03-01), Karl et al.
patent: 5304614 (1994-04-01), Winter et al.
patent: 5308815 (1994-05-01), Sangokoya
patent: 5324800 (1994-06-01), Welborn, Jr. et al.
patent: 5329032 (1994-07-01), Tran et al.
patent: 5350723 (1994-09-01), Neithamer et al.
patent: 5391790 (1995-02-01), Rohrmann et al.
patent: 5688734 (1997-11-01), Speca et al.
Experimental Methods in Catalyst Research, vol. 1, Academic Press, 1968, pp. 67-96.
Journal of Organometallic Chemistry, 369, 359-370 (1989).
Olefin Polymerization at Bis(pentamethylcyclopentadienyl)zirconium and hafnium centers: Chain-Transfer Mechanisms, Resconi, et al., J. Am. Chem. Soc., 1992, 114, 1025-1032.
"ansa-Zirconocene Polymerization Catalysts with Annelated Ring Ligands-Effects on Catalytic Activity and Polymer Chain Lengths", H. Brinzinger, et al., Organometallics 1994, 13, 964-970.
"The Influence of Aromatic Substituents on the Polymerization of Behavior of Bridged Zirconocene Catalysts", Spaleck, W., et al., Organometallics, 1994, 13, 954-963.
Copolymerization of poly(propylene) macromonomer and ethylene with metallocene catalysts, Shino, et al., Macromol. Symp. 97, 161-170 (1995).
Cationic Zirconocene Olefin Polymerization Catalysts Based on the Organo-Lewis Acid Tris(pentaflurorphenyl)borane. A Synthetic, Structural, Solution Dynamic, and Polymerizatioon Catalytic Study, Yang, et al., J. Am. Chem. Soc., 1994, 116, 10015-10031.
Bivariate chain length and long chain branching distribution for copolymerization of olefins and polyolefin chains containing terminal double-bonds, Macromol. Theory Simul. 5, 547-572 (1996).
Semicrystalline Polyolefins--Narrow MWD and Long Chain Branching: Best of Both Worlds, Antec, pp. 2234-2237, 1996.
Cationic Metallocene Polymerization Catalysts Based on Tetrakis (pentafluorophenyl)borate and Its Derivatives. Probing the Limits of Anion "Noncoordination" via a Synthetic, Solution Dynamic, Structural, and Catalytic Olefin Polymerization Study, Jia, et al., Organometallics, 1997, 16, 842-857.
Dekmezian Armen
Gadkari Avinash
Markel Eric J.
Peters David L.
Weng Weiqing
Exxon Chemical Patents Inc.
Lu Caixia
Muller W. G.
Peebles Brent M.
Wu David W.
LandOfFree
Vinyl-containing stereospecific polypropylene macromers does not yet have a rating. At this time, there are no reviews or comments for this patent.
If you have personal experience with Vinyl-containing stereospecific polypropylene macromers, we encourage you to share that experience with our LandOfFree.com community. Your opinion is very important and Vinyl-containing stereospecific polypropylene macromers will most certainly appreciate the feedback.
Profile ID: LFUS-PAI-O-97109