Nitrogen-containing perfluoralkanoyl peroxide and method for pro

Details Nitrogen-containing perfluoralkanoyl peroxide and method for pro Nitrogen-containing perfluoralkanoyl peroxide and method for pro

1992-12-28

1993-10-26

Cintins, Marianne M.

Organic compounds -- part of the class 532-570 series

Organic compounds

Amino nitrogen containing

C07C21115

Patent

active

052568253

ABSTRACT:
A nitrogen-containing perfluoroalkanoyl peroxide is provided which is represented by the formula: ##STR1## wherein Rf.sub.1 and Rf.sub.2 independently stand for an alkyl group of 1 to 5 carbon atoms, provided that Rf.sub.1 and Rf.sub.2 are joined to each other in one of the three patterns of union, 1) direct union, 2) union through the medium of an oxygen atom or 3) union through the medium of a nitrogen atom to form one of the three rings, i.e. five membered ring, six-membered ring or seven-membered ring. The nitrogen-containing perfluoroalkanoyl peroxide is produced by a method which comprises oxidizing a compound represented by the following formula: ##STR2##

REFERENCES:
Takamasa Fuchikami et al, "Direct Perfluoroalkylation of Functionalized Benzenes with Perfluoroalkyl Halides and Copper Bronze," Journal of Fluorine Chemistry, 22 (1983), pp. 541-556.
Zhao Chengxue et al, "Thermal Decomposition of Some Perfluoro- and Polyfluorodiacyl Peroxides," J. Org. Chem. (1982), 47, pp. 2009-2013.

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