Process for the preparation of low molecular weight copolymers o

Chemistry of hydrocarbon compounds – Unsaturated compound synthesis – By addition of entire unsaturated molecules – e.g.,...

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585507, 585513, 585523, 585700, 585728, 585733, 585 16, 585 18, C07C 232, C07C 222, C07C 238

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057289115

ABSTRACT:
A copolymer having an RSV less than 0.6 and a process for its preparation in which ethylene, at least one other 1-alkene and, optionally, an aliphatic or alicyclic polyunsaturated monomer are polymerized in the presence of a catalyst system containing (1) a compound of vanadium, (2) at least one alkyl aluminum halide, (3) an .alpha.-halo, ketoaromatic promoter and (4) a chain transfer agent in which the molar ratio of alkyl groups of the alkyl aluminum halide to halogen atoms is at least 1.5.

REFERENCES:
patent: 3574176 (1971-04-01), Boozer
patent: 3645993 (1972-02-01), Sunseri
patent: 4168358 (1979-09-01), Harada et al.
patent: 4435552 (1984-03-01), Evens

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