Enhanced photocatalytic conversion of methane to methanol using

Liquid purification or separation – Processes – Utilizing electrical or wave energy directly applied to...

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210758, 210763, 210760, 2041573, 2041579, 502 5, C02F 132, C07C 2948

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active

061562114

ABSTRACT:
A method and apparatus for the conversion of methane in solution or gas provides photochemical conversion in a unique two-phase or three-phase boundary system formed in each pore of a semiconductor membrane in a photocatalytic reactor. In a three-phase system, gaseous oxidant, methane contained in a liquid, and solid semiconductor photocatalyst having a metal catalyst disposed thereon meet and engage in an efficient conversion reaction. The porous membrane has pores which have a region wherein the meniscus of the liquid varies from the molecular diameter of water to that of a capillary tube resulting in a diffusion layer that is several orders of magnitude smaller than the closest known reactors.

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