Polycyclic diamines and method of preparation

Organic compounds -- part of the class 532-570 series – Organic compounds – Heterocyclic carbon compounds containing a hetero ring...

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546 14, 546 22, C07D22122

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active

051244543

ABSTRACT:
Polycyclic diamines, incorporating a basic framework similar to [3.3.3]propellane, and derivatives of the basic polycyclic diamines and a process for preparing same are provided. The diamines are prepared by subjecting bispyridine compounds to electroreductive coupling in an acidic solution. The polycyclic diamines and derivatives thereof are useful as chain extenders, crosslinking agents and curatives in various polymer systems.

REFERENCES:
patent: 1947732 (1934-02-01), Parkes
patent: 4194046 (1989-03-01), Junghans
patent: 4929622 (1990-05-01), Allen et al.
Synthesis of Pyridines by Electrochemical Methods: by J. E. Toomey, Jr. in Advances in Heterocyclic Chemistry, vol. 37, 1984, pp. 167-215.
Nonaka, et al., Electrochemical Acta, 1977, 22, pp. 271-277.
Ferles, et al., Collect. Czech. Chem. Commun., 1975, p. 2183.

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