Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – Polymers from only ethylenic monomers or processes of...
Patent
1995-05-19
1996-03-26
Nagumo, Mark
Synthetic resins or natural rubbers -- part of the class 520 ser
Synthetic resins
Polymers from only ethylenic monomers or processes of...
526132, 526134, 526160, 526126, 526170, 526351, 526352, 526904, C08F 469, C08F 468
Patent
active
055021247
ABSTRACT:
This invention relates to processes using non-Group 4 transition metal compositions useful as olefin polymerization catalysts, wherein the transition metal is in a high oxidation state. The invention further relates to design of new ligand systems and methods of preparing and using the same. Compositions useful as catalyst precursors are neutral transition metal complexes comprising the unique ligand systems of the invention. The inventive compositions may be activated to a catalytic state by ion-exchange reagents or by Lewis acids.
REFERENCES:
patent: 4530914 (1985-07-01), Ewen et al.
patent: 4701432 (1987-10-01), Welborn, Jr.
patent: 4892851 (1990-01-01), Ewen et al.
patent: 5006500 (1991-04-01), Chang
patent: 5008228 (1991-04-01), Chang
patent: 5017714 (1991-05-01), Welborn, Jr.
patent: 5036034 (1991-07-01), Ewen
patent: 5155080 (1992-10-01), Elder et al.
patent: 5162466 (1992-11-01), Kaval et al.
patent: 5194534 (1993-03-01), Bell
patent: 5198401 (1993-03-01), Turner et al.
patent: 5320996 (1994-06-01), Carney et al.
Thomas et al., "Paramagnetic Alkylchromium Compounds as Homogeneous Catalysts for the Polymerization", 1991, pp. 893-902, J. Am. Chem. Soc., vol. 113.
Herberich, G. E., Comprehensive Organometallic Chemistry, The Synthesis, Reactions and Structures of Organometallic Compounds, vol. 1, pp. 381-410, Pergamon Press, Oxford.
Schmidt, Gregory F., and Maurice Brookhart, Implications of Three-Center, Two-Election M-H-C Bonding for Related Alkyl Migration Reactions: Design and Study of an Ethylene Polymerization Catalyst, J. Am. Chem. Soc. 1985, 107, pp. 1443-1444.
Devore et al., Complexes of (Arylimido)vanadium(V). Synthetic, Structural, Spectroscopic, and Theoretical Studies of V(Ntol)Cl.sub.3 and Derivatives, J. Am. Chem. Soc. 1987, 109, pp. 7408-7416.
Ballard et al., Alkyl Bridged Complexes of the Group 3A and Lanthanoid Metals as Homogenous Ethylene Polymerisation Catalysts, Journal of The Chemical Society, Chemical Communications, 22, 1978, pp. 994-995.
Shapiro et al., Unique Example of a Single-Component.varies.-Olefin Polymerization, Organometallics 1990, 9, p. 867-869.
Canich Jo Ann M.
Crowther Donna J.
Fisher Richard A.
Hlatky Gregory G.
Turner Howard W.
Exxon Chemical Patents Inc.
Nagumo Mark
Reid F. E.
Spiering M. S.
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