Process for preparing phenoxybenzoic acids

Organic compounds -- part of the class 532-570 series – Organic compounds – Carboxylic acid esters

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562434, 562438, 562416, C07C 7946

Patent

active

044018282

ABSTRACT:
This process relates to the oxidation of phenoxytoluenes to phenoxybenzoic acids utilizing a hydrogen peroxide activated, bromide promoted cobalt catalyst which can be performed at atmospheric pressure and at moderate temperatures. These phenoxybenzoic acids can then be esterified and selectively nitrated to give the corresponding 2-nitro-5-substituted)phenoxybenzoic acid esters. Alternatively the acids can be nitrated and then esterified.

REFERENCES:
patent: 2245528 (1941-06-01), Loder
patent: 2992271 (1961-06-01), Hay
patent: 3139452 (1964-06-01), Hay
patent: 3708531 (1973-01-01), Croce
patent: 3907866 (1975-09-01), Theissen

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