Polymerization of 1,3-cyclodiene with vinylaromatic hydrocarbon

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – Polymers from only ethylenic monomers or processes of...

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260 304A, 260880B, 526 25, 526 26, 526 84, 526173, 526180, 526181, 526283, 526293, 526308, C08F 408, C08F 804, C08F21208, C08F23206

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041385365

ABSTRACT:
A 1,3-cyclodiene is polymerized with a vinylaromatic hydrocarbon in the presence of a paraffin or cycloparaffin hydrocarbon diluent and an organolithium initiator. Further, polymerization of a 1,3-cyclodiene with a vinylaromatic hydrocarbon employing an organolithium initiator having a functionally greater than 1 produces a new and useful copolymer. Hydrogenated copolymers are provided.

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patent: 3787510 (1974-01-01), Farrar
patent: 3842145 (1974-10-01), Hsieh
Polymer Chemistry of Synthetic Elastomers, Forman, Part II (Interscience, 1969), pp. 491-596.
Vinyl Polymerization, Part II (Marcel Dekker, N.Y., 1969), pp. 211-229.
Fortschritte der Hochpolymeren, Bywater, 4 (1965), pp. 66-110.

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