Process for the manufacture of gasoline

Chemistry of carbon compounds – Miscellaneous organic carbon compounds – C-metal

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208 11LE, 208135, 208141, 260449R, 260449M, 260449L, 2604495, 260671R, 26071C, 260671M, 260673, 2606735, 260682, 252455Z, C07C 1800

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041384423

ABSTRACT:
Synthesis gas comprising a mixture of carbon monoxide and hydrogen is derived from fossil fuels and catalytically converted in a first reaction zone to a mixture of methanol and dimethyl ether which in turn is converted in a separate reaction zone in contact with a crystalline aluminosilicate zeolite catalyst having a silica to alumina ratio of at least about 12 and a constraint index of about 1 to 12, and preferably a crystal density in the hydrogen form of not substantially below about 1.6 grams per cubic centimeter to a product which is resolved into a high octane gasoline fraction, a light hydrocarbon gas fraction which may be liquefied and a hydrogen-rich gaseous by-product which is recycled to the conversion of fossil fuels to synthesis gas or may be otherwise used.

REFERENCES:
patent: 1558559 (1925-10-01), Mittasch
patent: 3728408 (1973-04-01), Tobias
patent: 3894105 (1975-07-01), Chang et al.
patent: 3922215 (1975-11-01), Linden et al.
patent: 4076761 (1978-02-01), Chang et al.

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