Preparation of N-substituted amino acids

Details Preparation of N-substituted amino acids Preparation of N-substituted amino acids

1985-09-23

1987-08-04

Evans, J. E.

Chemistry of carbon compounds

Miscellaneous organic carbon compounds

C-metal

562556, 562564, 562567, 562571, 562574, 562575, C07F 936

Patent

active

046844830

ABSTRACT:
An N-substituted amino acids can be prepared by the steps of: bringing together under reaction condition glyoxal and a source of sulfur dioxide in an aqueous medium to produce a sulfonated intermediate; and introducing into said medium a nitrogen compound selected from the group consisting of ammonia, a primary amine, and a secondary amine, into said medium containing said intermediate to produce said N-substituted amino acid.

REFERENCES:
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patent: 4486358 (1984-12-01), Moser
Maurer & Woltersdorf, "Formation of Amino Acids from .alpha.-Dicarbonyl Compounds", Z. Physiol. Chem., 254, 18-24 (1938).

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