Synthesis of thiazoles

Details Synthesis of thiazoles Synthesis of thiazoles

1983-05-12

1984-08-28

Gerstl, Robert

Organic compounds -- part of the class 532-570 series

Organic compounds

Heterocyclic carbon compounds containing a hetero ring...

544133, 546209, 548202, C07D27714, C07D27728

Patent

active

044685173

ABSTRACT:
Certain 4-halomethylthiazoles having a 2-substituted-aminomethyl group are prepared by reacting an aminothioamide with a dihalopropanone in the presence of a haloalkane and a bicarbonate, and dehydrating the resulting intermediate.

REFERENCES:
patent: 3391151 (1968-07-01), Davis
Hooper and Johnson, J. Am. Chem. Soc., 56, 470-471, (1934).
Chi and Tshin, J. Am. Chem. Soc., 64, 90-91, (1942).
Goldberg and Kelly, J. Chem. Soc., 1372-1377, (1947).
Caldwell and Fox, J. Am. Chem. Soc., 73, 2935-2936, (1951).

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