Chemistry of carbon compounds – Miscellaneous organic carbon compounds – C-metal
Patent
1979-12-14
1981-04-28
Trousof, Natalie
Chemistry of carbon compounds
Miscellaneous organic carbon compounds
C-metal
560 41, 560171, 562450, 562522, C07C10200
Patent
active
042645158
ABSTRACT:
A N-acyl .alpha.-amino acid is manufactured by reacting an unsaturated vegetable oil or a C.sub.8 -C.sub.30 mono-olefinic compound with an amide, carbon monoxide and hydrogen, in the presence of a cobalt catalyst. The process is operated in one step, providing for an increased selectivity as compared with a two-step process.
REFERENCES:
patent: 2820059 (1958-01-01), Hasek
patent: 2834812 (1958-05-01), Hughes
patent: 3766266 (1973-10-01), Wakamatsu
Fell, Tetrahedron Letters, p. 3261, (1968).
Ullmanns, "Encyklopaedieder Technischen Chemie," Chem. vol. 7, p. 122.
Abst. 52:14661 (1958).
Wakamatsu, J. Chem. Soc., D, p. 1540, (1971).
Murachashi, Bull. Chem. Soc., Jap., 33, pp. 78-80 (1960).
Chauvin Yves
Commereuc Dominique
Hirschauer Andre
Stern Robert
Institut Francais du Pe'trole
Shippen Michael
Trousof Natalie
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