Oxidation of organic compounds using ceric ions in aqueous metha

Details Oxidation of organic compounds using ceric ions in aqueous metha Oxidation of organic compounds using ceric ions in aqueous metha

1986-05-05

1987-01-27

Demers, Arthur P.

Chemistry: electrical and wave energy

Processes and products

204 78, 260369, 260385, 568309, 568426, C25B 302

Patent

active

046392980

ABSTRACT:
A process for oxidizing aromatic and alkyl substituted aromatic compounds to carbonyl containing compounds by contacting an aromatic and alkyl aromatic compound with an aqueous solution of ceric methanesulfonate having from at least 1.5 to 9 molar concentration of free acid of methanesulfonic acid and at least 0.2 molar cerium ion concentration. The present process provides a highly effective means of forming the desired carbonyl containing product in good yields and high selectivity.

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Marrocco et al., J. Org. Chem., 1983, 48, pp. 1487-1491.

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