Process for the preparation of omega-unsaturated carboxylic acid

Details Process for the preparation of omega-unsaturated carboxylic acid Process for the preparation of omega-unsaturated carboxylic acid

1987-01-27

1989-07-04

Lone, Werren B.

Chemistry of carbon compounds

Miscellaneous organic carbon compounds

C-metal

260408, 260413, 562602, C09F 500

Patent

active

048452718

ABSTRACT:
An improved method for the synthesis of omega-unsaturated carboxylic acids is disclosed which precludes double bond migration or hydrogenation in order to prepare a high purity product necessary for high resolution in forming a resist by electron beam microlithography. This result can be obtained by a coupling reaction between a Grignard reagent of an unsaturated organochloride compound as defined in the application with a halo magnesium salt of a long chain organic acid.

REFERENCES:
patent: 2921939 (1960-01-01), Ramsden
patent: 4144397 (1979-03-01), Mathews et al.
Barraud, A. et al., J. Colloid Interface Sci., 1977, 62, 509.
Barraud, A. et al., Thin Solid Films, 1980, 68, 91.
Barraud, A. et al., Solid State Tech., 1979, Aug. 120.
Fariss, G. et al., Thin Solid Films, 1983, 99, 305.
Peterson, I. R. et al., Thin Solid Films, 1983, 109, 371.
Stenhagen, E., Arkiv Kemi, Min. O. Geol., 1949, 1 (13), 99.
Bowman, R. et al., J. Chem. Soc., 1952, 3945.
Sisido, K. et al., J. Org. Chem., 1962, 27, 3722.
Hunig, S. et al., Ber. 1962, 95, 2498.
Gunstone et al., Chem. Phys. Lipids, 1967, 1, 209.
Huisgen, R. et al., Tetrahedron, 1959, 6, 253.
Smissman, E. et al., J. Org. Chem., 1964, 29, 3517.
Joycelyn, P. et al., J. Org. Chem., 1953, 132.
Organic Synthesis, Collect., vol. I, Wiley, New York, N.Y., 1941, p. 29.
Bergbreiter, D. et al., J. Org. Chem., 1975, 40, 779.
Baer, T. et al., Tetrahedron Letters, 1976, 4697.

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