Novel metal-diketone absorbents for carbon monoxide or olefins

Details Novel metal-diketone absorbents for carbon monoxide or olefins Novel metal-diketone absorbents for carbon monoxide or olefins

1988-03-14

1989-07-04

Shippen, Michael L.

Organic compounds -- part of the class 532-570 series

Organic compounds

Heavy metal containing

556 40, C07F 108, C07F 110

Patent

active

048452548

ABSTRACT:
Novel compounds for absorbing carbon monoxide and olefinically-unsaturated compounds from feedstreams are of the formula ##STR1## wherein R.sub.1 is trichloromethyl or R.sub.F ; R.sub.F is C.sub.n F.sub.2n+1 and n is 1-8; R.sub.2 is H or hydrocarbyl of 2-20 carbon atoms having at least one olefinic unsaturated bond; M.sup.I is Cu.sup.I or Ag.sup.I and R.sub.3 is hydrocarbyl of 2-20 carbon atoms having at least one olefinic unsaturated bond.

REFERENCES:
patent: 2892681 (1959-06-01), Crandall
patent: 3272853 (1966-09-01), Brawn
patent: 3320294 (1967-05-01), Larson
patent: 3401112 (1968-09-01), Dunlop et al.
patent: 3424772 (1969-01-01), Moshier
patent: 3578619 (1971-05-01), Reeder
patent: 3592865 (1971-07-01), Long et al.
patent: 3764274 (1973-10-01), Lucid
patent: 3794433 (1974-02-01), Seeley
patent: 3864407 (1975-02-01), Yates
patent: 3867418 (1975-02-01), Burgett
patent: 4180386 (1979-12-01), McCormack
patent: 4279874 (1981-07-01), Doyle
patent: 4385005 (1983-05-01), Doyle
patent: 4424352 (1984-01-01), Siedle
patent: 4434317 (1984-02-01), Doyle et al.
patent: 4471152 (1984-09-01), Doyle et al.
patent: 4508694 (1985-04-01), Doyle et al.
Doyle et al., Organometallics, vol. 4 (1985), pp. 830-835.
Walker, Chemtech, May 1975, pp. 308-311.
Bertholet, Ann. de Chim. et de Phys., 7th series, vol. XXIII (May, 1901), pp. 32-39.
Bruce, J. Organometal. Chem., vol. 44 (1972), pp. 209-226.
Gilland et al., J. Am. Chem. Soc. vol. 61 (1941), pp. 1960-1962; vol. 63 (1941), pp. 2088-2090.
Hurtado et al., Transition Metal Chem., vol. 2 (1977), pp. 91-94.
Hartley et al., J. Chem. Soc. Dalton (1977), pp. 469-477.
Liebig, Ann. der Pharmacie, vol. IX (1834), pp. 1-39; vol. 23 (1837), pp. 12-42.
Lu're et al., Sinet. Kauchuk, vol. 3 (1934), pp. 19-29.
Winstein et al., J. Am. Chem. Soc., vol. 60 (1938), pp. 836-847.
Kamitori et al., Synthesis, (Apr., 1986), pp. 340-342.
Vorob'eva et al., Chem. Abs., 54:9987i.

Affiliated with

Also associated with

Rating

Novel metal-diketone absorbents for carbon monoxide or olefins does not yet have a rating. At this time, there are no reviews or comments for this patent.

If you have personal experience with Novel metal-diketone absorbents for carbon monoxide or olefins, we encourage you to share that experience with our LandOfFree.com community. Your opinion is very important and Novel metal-diketone absorbents for carbon monoxide or olefins will most certainly appreciate the feedback.

Rate now

Comments { 0 }

Profile ID: LFUS-PAI-O-853932