Preparation of 8-bromomethyl-3-methylquinoline compounds

Details Preparation of 8-bromomethyl-3-methylquinoline compounds Preparation of 8-bromomethyl-3-methylquinoline compounds

1988-01-21

1989-07-04

Springer, David B.

Organic compounds -- part of the class 532-570 series

Organic compounds

Heterocyclic carbon compounds containing a hetero ring...

422186, 546170, C07D21518

Patent

active

048452262

ABSTRACT:
A process for the preparation of 8-bromomethyl-3-methylquinoline compounds of the formula I ##STR1## where one of both substituents X are chlorine and, where relevant, the other substituent X is hydrogen, by bromination of the corresponding 8-methylquinoline compound in the presence of a 2-phase mixture of a solvent stable to bromination and of, preferably, buffered water.

REFERENCES:
Fuson, "Adv. Org. Chem.", Wiley, New York, N.Y., pp. 30-35, 288 and 289 (1950).
Chemical Abstract, vol. 199, No. 7, p. 167, 51427 (1984).

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