Process for the preparation of 4-aminodiphenylamine

Organic compounds -- part of the class 532-570 series – Organic compounds – Amino nitrogen containing

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564415, 564433, 564434, C07C20930

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059327685

ABSTRACT:
4-aminodiphenylamines are prepared by hydrogenating nitrosobenzene or mixtures of nitrosobenzene and nitrobenzene with hydrogen in the presence of bases containing hydroxide, oxide and/or alkoxide groups and heterogeneous catalysts in inert aprotic solvents at temperatures of from 0 to 200.degree. C. and at pressures of from 0.1 to 150 bar.

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Ullmann's Encyclopedia of Industrial Chemistry, Antioxidants, Peter P. Klemchuk, vol. A3, pp. 91-111 (1985).
Kirk-Othmer, 4.sup.th Ed., vol. 3, Antiozonants, Robert P. Lattimer, et al., pp. 448-456 (1992).
Kirk-Othmer, 4.sup.th Ed., vol. 3, Antioxidants, Martin Dexter, pp. 424-427 (1992).

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