Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – Polymers from only ethylenic monomers or processes of...
Patent
1988-12-29
1990-10-16
Schofer, Joseph L.
Synthetic resins or natural rubbers -- part of the class 520 ser
Synthetic resins
Polymers from only ethylenic monomers or processes of...
5263072, C08F 3004
Patent
active
049636324
ABSTRACT:
A homogeneous micellar free radical polymerization process for the formation of a terpolymer having the structure of: ##STR1## wherein S is selected from the group consisting of SO.sub.3 M, phenyl SO.sub.3 M, CONHC(CH.sub.3).sub.2 CH.sub.2 SO.sub.3 M or COOM; M is selected from the group consisting of Groups IA, 1B, IIA and IIB of the Periodic Table of Elements, R.sub.1 is a C.sub.1 to C.sub.10 alkyl, cycloalkyl or aralkyl group, R.sub.2 is hydrogen or a C.sub.4 to C.sub.18 alkyl, cycloalkyl or aralkyl group, x is about 10 to about 90 mole %, y is about 0.1 to about 60 mole %, and z is about 0.2 to about 10 mole % which comprises the steps of forming a mixture of an anionic surfactant, a nonionic surfactant, ##STR2## under a nitrogen atmosphere; adding deoxygenated water to said mixture to form a homogeneous reaction solution; adding free radical initiator to said homogeneous reaction solution to initiate polymerization of said monomers; terpolymerizing said monomers at a sufficient temperature and for a sufficient period of time to form said terpolymer and without the formation of substantial amounts of particulates or phase separation occurring.
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Bock Jan
Valint Paul L.
Exxon Research and Engineering Company
Nanfeldt Richard E.
Sarofim N.
Schofer Joseph L.
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