Block copolymers of polysiloxanes and copolymers of conjugated d

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – At least one aryl ring which is part of a fused or bridged...

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525100, 525105, 525106, 525479, 528 14, 528 25, 526275, C08G 7704

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active

059326492

ABSTRACT:
Block copolymers are described which comprise alternating blocks of (A) a polysiloxane; and (B) a copolymer of a 1,3-conjugated diene and a monovinyl aromatic compound. The block copolymers can be prepared by reacting a polysiloxane with a dilithiated copolymer of a conjugated diene and a monovinyl aromatic compound and thereafter neutralizing the reaction product with a protonic acid or a polyfunctional alkyl silane or silicon tetrachloride. Cured elastomer compositions exhibiting surface release characteristics are obtained by curing a mixture comprising the above-described block copolymer in the presence of a curing system comprising a peroxide and sulfur. Multilayer elastomer structures useful in manufacturing articles from elastomeric materials also are described wherein at least a portion of an outer layer of the multilayer elastomer structure has release characteristics and comprises the cured block copolymers of the present invention.

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