Olefin oxidation with methyl formate solvent

Details Olefin oxidation with methyl formate solvent Olefin oxidation with methyl formate solvent

1979-01-12

1983-04-19

Milestone, Norma S.

Organic compounds -- part of the class 532-570 series

Organic compounds

Heterocyclic carbon compounds containing a hetero ring...

C07D30106

Patent

active

043806597

ABSTRACT:
An olefinically unsaturated compound containing from 3 up to about 18 carbon atoms per molecule and having the formula ##STR1## wherein each R.sub.1, R.sub.2, R.sub.3 and R.sub.4 is independently selected from a group consisting of hydrogen, alkyl, and cycloalkyl radicals and wherein there is at least one hydrogen attached to a carbon atom adjacent to the olefinic group is oxidized in a liquid reaction medium containing methyl formate. In a preferred embodiment of the invention propylene is oxidized in the presence of methyl formate solvent.

REFERENCES:
patent: 3275662 (1966-09-01), Gash
patent: 3281433 (1966-10-01), Reid
patent: 3477919 (1969-11-01), Lichtenwalter et al.
patent: 3818051 (1974-06-01), Balepin et al.
F. Lanos et al., Chimie et Industrie (Paris) 91, 47-56 (1964) (Transl).
E. G. Hancock, Ed., John Wiley & Sons, N.Y. (1973), Propylene and its Industrial Derivatives, Chapter 7, pp. 273-297.
F. W. Meadus et al., Canadian Jour. Chem. Eng., vol. 42, Apr. 1964, pp. 86-87.

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