Chemistry of carbon compounds – Miscellaneous organic carbon compounds
Patent
1972-09-27
1976-03-09
Henderson, Jr., Christopher A.
Chemistry of carbon compounds
Miscellaneous organic carbon compounds
8 4, 162168NA, 210 54, 260 22R, 260 803N, 260 857, 260 861N, 260 897N, 260897R, C08F 390, C08F 1502
Patent
active
039431142
ABSTRACT:
N-3-Aminoalkyl propionamides with an ether substituent on the beta carbon atom are prepared by the reaction of analogous N-3-oxohydrocarbon-substituted amides with an amine in the presence of a reducing agent, preferably hydrogen and a hydrogenation catalyst. The resulting compounds can be converted to acrylamides by pyrolysis in the presence of a strong base. The latter compounds may also be prepared by the reaction of a .beta.,.gamma.-unsaturated amine with an acrylonitrile in the presence of sulfuric acid. They are useful for improving dyeability of fiber-forming polymers and may be polymerized to form compositions which are useful in paper manufacture and (in their quaternized form) are excellent flocculants.
REFERENCES:
patent: 2980657 (1961-04-01), Melamed
patent: 3044998 (1962-07-01), Emrick
patent: 3318953 (1967-05-01), Wehrmeister
Adams, Jr. James W.
Henderson, Jr. Christopher A.
Pittman William H.
The Lubrizol Corporation
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