Preparation of tertiary butyl alcohol by the catalytic decomposi

Details Preparation of tertiary butyl alcohol by the catalytic decomposi Preparation of tertiary butyl alcohol by the catalytic decomposi

1987-09-08

1990-05-01

Garner, Vivian

Organic compounds -- part of the class 532-570 series

Organic compounds

Oxygen containing

568910, 568914, 568922, 568571, 502167, C07C 3112, C07C 29132, C07C 2988, C07C 2704

Patent

active

049220330

ABSTRACT:
A tertiary butyl hydroperoxide feedstock, such as one prepared by the reaction of isobutane with molecular oxygen comprising tertiary butyl hydroperoxide dissolved in tertiary butyl alcohol, is charged to a catalytic decomposition zone where the tertiary butyl hydroperoxide is catalytically decomposed in the presence of a soluble ruthenium catalyst compound promoted with a bidentate ligand to provide a decomposition reaction product characterized by a high conversion rate and a high selectivity of tertiary butyl hydroperoxide to tertiary butyl alcohol.

REFERENCES:
patent: 3360585 (1967-12-01), Winnick
patent: 3505360 (1970-04-01), Allison et al.
patent: 4508923 (1985-04-01), Taylor et al.
patent: 4547598 (1985-10-01), Sanderson et al.
patent: 4551553 (1985-11-01), Taylor et al.

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