Organic compounds -- part of the class 532-570 series – Organic compounds – Oxygen containing
Patent
1986-09-12
1988-04-26
Lone, Werren B.
Organic compounds -- part of the class 532-570 series
Organic compounds
Oxygen containing
568455, C07C 4550
Patent
active
047406267
ABSTRACT:
The present invention relates to a process for the preparation of aldehydes by the reaction of olefinic compounds with hydrogen and carbon monoxide in the presence of a catalyst system containing rhodium and aromatic phosphines. The aromatic phosphines are soluble in organic media and represent salts of sulfonated or carboxylated triarylphosphines which are insoluble in water. After hydroformylation, the reaction product is treated with a diluted aqueous solution of a base and the aqueous phase containing rhodium and aromatic phosphines is separated. Thus, thermal loading of the catalyst, for example by the redistillation of the reaction product, is avoided.
REFERENCES:
patent: 4248802 (1981-02-01), Kuntz
patent: 4399312 (1983-09-01), Russell et al.
patent: 4487972 (1984-12-01), Haag et al.
patent: 4510332 (1985-04-01), Matsumoto
patent: 4578523 (1986-03-01), Bahrmann et al.
patent: 4593126 (1986-06-01), Cornils et al.
Bach Hanswilhelm
Bahrmann Helmut
Bexten Ludger
Konkol Werner
Weber Jugen
Bierman Jordan B.
Lone Werren B.
Ruhrchemie Aktiengesellschaft
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