Method for making tetrahydroxydiphenylsulfide and product obtain

Organic compounds -- part of the class 532-570 series – Organic compounds – Amino nitrogen containing

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568 44, 568 48, C07C14930

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active

047147806

ABSTRACT:
Thiobisphenols, such as 2,2-bis[2,2-bis(4-hydroxyphenyl)propane]-sulfide are provided by effecting reaction betwen a dihydric phenol such as bisphenol-A and sulfur dichloride in the presence of an effective amount of a Lewis acid catalyst and organic solvent.

REFERENCES:
patent: 3060121 (1962-10-01), Orloff et al.
patent: 4115590 (1978-09-01), Lerner
patent: 4380671 (1983-04-01), Yamaguchi et al.
Hiroshi Kato, "Tetrahydroxydiphenyl Sulfide", Chemical Abstracts 88, #88:50470r (1978), p. 511.
"Prepn. of 2,2'-thio-bisphenol Derivs.", Derwent Pub. Ltd., Central Patents Index 83, #39, A+:Polymer Applications #J8 3042866-B (1983).
"Thiobis-phenol(s) & Resorcinol(s) Prodn.", Derwent Pub. Ltd., Central Patents Index, Week 8402, AE: Polymer+General Chemistry #FR 2527-603-A (1983).
Akihiro Yamaguchi et al., "Bis-(4-substituted Phenol)Sulfides", Chemical Abstracts 93, #93:149974y (1980), p. 692.
Akihiro Yamaguchi et al, "Preparation of 2,2'-bis(4-substituted-phenol Sulfides", Chemical Abstracts 94, #94:83765t (1981) p. 691.

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