Cyano- and polycyanometallo-porphyrins as catalysts for alkane o

Details Cyano- and polycyanometallo-porphyrins as catalysts for alkane o Cyano- and polycyanometallo-porphyrins as catalysts for alkane o

1992-06-02

1993-05-18

Cintins, Marianne M.

Organic compounds -- part of the class 532-570 series

Organic compounds

Heterocyclic carbon compounds containing a hetero ring...

C07D48722

Patent

active

052123006

ABSTRACT:
New compositions of matter comprising cyano-substituted metal complexes of porphyrins are catalysts for the oxidation of alkanes. The metal is iron, chromium, manganese, ruthenium, copper or cobalt. The porphyrin ring has cyano groups attached thereto in meso and/or .beta.-pyrrolic positions.

REFERENCES:
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patent: 4970348 (1990-11-01), Ellis et al.
patent: 5118886 (1992-06-01), Ellis et al.
Yamaguchi et al., Inorg. Chem. (1992) 31, 3216-3222.
Kadish et al., Inorg. Chem. (1985), 24, 2148-2156.
P. E. Ellis, Jr. and J. E. Lyons, Catalysis Letters, 8, 45 (1991).
H. J. Callot, (1) Bull. Soc. Chim. de France 1974 No. 7-8, pp. 1492-1496.

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