High selectivity cyanoethylation process

Chemistry of carbon compounds – Miscellaneous organic carbon compounds – C-metal

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260464, C07C12000, C07C12134

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active

041713222

ABSTRACT:
An improvement in the cyanoethylation process using a bed of basic ion exchange resin catalyst wherein the conversion of the acrylonitrile is limited to the range between from about 60% to about 96%. A monoadduct intermediate can be recycled. As a result of the limitation to the conversion selectivity as to the desired product is in excess of 95%. The improved process, e.g., has a selectivity of 98% when the conversion is about 82% and the reactants are acrylonitrile and ethylene glycol.

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Cyanoethylation; Kirk-Othmer, Encyclopedia of Chemical Technologg, 2nd ed., vol. 6, 1965, pp. 634-664.
Bruson, Org. Reactions, vol. 5, 1949, pp. 79-113.
Chem. J. Org. Chem., 27, (1962), pp. 1920-1921.

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