Production of alkyl esters of saturated aliphatic carboxylic aci

Details Production of alkyl esters of saturated aliphatic carboxylic aci Production of alkyl esters of saturated aliphatic carboxylic aci

1981-08-11

1983-12-13

Sneed, Helen M. S.

Chemistry of carbon compounds

Miscellaneous organic carbon compounds

C-metal

C11C 302

Patent

active

044204299

ABSTRACT:
A process for the production of alkyl esters of saturated aliphatic carboxylic acids made by reacting olefins with carbon monoxide and alkanol in the presence of a catalyst consisting of a cobalt compound and a promoter selected from pyridine, a non-ortho-substituted alkylpyridine or mixtures thereof at elevated pressure and temperature and with feedback of unconverted input materials, the water contained in the reaction mixture being separated as much as possible during the reprocessing from the flows of substances slated for feedback.

REFERENCES:
patent: 2076111 (1937-04-01), Bannister
patent: 3507891 (1970-04-01), Hearne
patent: 3906016 (1975-09-01), Isa
patent: 4041057 (1977-08-01), Fanning
Peter Hofmann et al., "Hydrocarboxymethylation-An Attractive Route from Olefins to Fatty Acid Esters?" Sep. 1980, I & EC Product Research & Development, vol. 19, p. 330-334.

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