Method of controlling molecular weight distribution of polytetra

Organic compounds -- part of the class 532-570 series – Organic compounds – Oxygen containing

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568621, C07C 4134, C07C 4138

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active

052986705

ABSTRACT:
Polytetramethylene ether glycols (PTMEG) are fractionated with liquid propane in an extractor under high pressure. Fractions are separated by altering the extraction pressure, which alters the solvent power of the propane. The polydispersities of all extracted PTMEG fractions are generally below 1.3. The addition of a cosolvent, preferably tetrahydrofuran, can effectively lower the initial extraction pressure and increase the efficiency of the extraction.

REFERENCES:
patent: 4306058 (1981-12-01), Copelin
patent: 4500705 (1985-02-01), Copelin
patent: 4762951 (1988-08-01), Mueller
patent: 4933503 (1990-06-01), Mueller
patent: 5053553 (1991-10-01), Dorai et al.

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