Mild-cure formaldehyde-free durable-press finishing of cotton te

Bleaching and dyeing; fluid treatment and chemical modification – Chemical modification of textiles or fibers or products thereof – Cellulose fibers

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8DIG17, D06M 1312

Patent

active

044721676

ABSTRACT:
The use of glycols as coreactive additives with glyoxal in the aluminum sulfate-catalyzed crosslinking of cotton cellulose in the presence of alpha-hydroxy acids as catalyst activators at moderate curing temperatures is disclosed. The cotton textiles so treated are free from the discoloration and excessive tendering produced by glyoxal in the presence of metal salt catalysts at high temperature, are non-nitrogenous and formaldehyde-free, and exhibit high levels of wrinkle resistance and smooth drying properties without the formaldehyde release characteristic of N-methylolamide finishing agents.

REFERENCES:
patent: 2826514 (1958-03-01), Schroeder
patent: 3434794 (1969-03-01), Tovey
patent: 3451763 (1969-06-01), Weiss
patent: 4269603 (1981-05-01), Worth
Llwood J. Gonzales and John D. Guthrie, "Crosslinking Cotton Cellulose with Glyoxal Reaction Products", American Dyestuff Reporter 58 [3] 27-29 (1969).
Pastyr et al., Chemical Abstracts 89 131030v, "Modification of Hydroxyethyl Cellulose Fibers and Foils" (1978).
Welch, Clark M. and Forthright Danna, "Glyoxal as a Non-Nitrogenous Formaldehyde-Free Durable-Press Reagent for Cotton" Textile Research Journal 52 149-157 (1982).
U. Meyer et al., "Comparison of Catalytic Activities and Textile Mechanical Properties Observed in the Crosslinking of Cotton with Highly Active Catalysts", Textile Research Journal 46 691-697 (1976).
Meyer et al., "Comparison of Textile Mechanical Properties of Cotton in Crosslinking with Dimethylolethyleneurea and Formaldehyde", Textile Research Journal 46 813-817 (1976).

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