Polyimide and high-temperature adhesive of polyimide based on me

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – From phenol – phenol ether – or inorganic phenolate

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528125, 528128, 528172, C08G 7310

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active

050876899

ABSTRACT:
Polyimide having repeating units of the following formula (I) and its polyamic acid precursor having repeating units of the following formula (II) are disclosed; ##STR1## (where Y is a radical selected from the group consisting of a bond, divalent hydrocarbon having 1 to 10 carbons, hexafluorinated isopropylidene, carbonyl, thio, sulfinyl, sulfonyl and oxide, and R is a tetra-valent radical selected from the group consisting of aliphatic radical having 2 and more carbons, cyclo-aliphatic radical, monoaromatic radical, condensed polyaromatic radical, and noncondensed polyaromatic radical wherein aromatic radicals are mutually connected with a bond or a crosslinking function).
Typical examples of polyimide and polyamic acid include where Y is thio radical and R is ##STR2## Y is a bond and R is III or IV, and Y is isopropylidene radical and R is IV.
The polymers can be prepared from corresponding diamine and tetracarboxylic acid dianhydride.
Polyimide or polyamic acid of this invention is excellent for high-temperature adhesive.

REFERENCES:
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patent: 4065345 (1977-12-01), Progar et al.
patent: 4111906 (1978-09-01), Jones et al.
patent: 4196144 (1980-04-01), Darms
patent: 4203922 (1980-05-01), Jones et al.
patent: 4477648 (1984-10-01), Jones et al.
patent: 4535101 (1985-08-01), Lee et al.
patent: 4696994 (1987-09-01), Nakajima et al.
patent: 4795798 (1989-01-01), Tamai et al.
Bell, Journal of Polymer Science: Polym. Chem. Ed. 14, 2275-2292, (1976).
Bell, ibid. 14 225-235, (1976), (Bell II).
Chemical Abstracts, 100:193178d (1984).

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