Coating compositions of polymers of vinyl oxazoline drying oil e

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – At least one aryl ring which is part of a fused or bridged...

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524 95, 524597, 526258, C08L 110, C08L 114, C09D 374

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043682898

ABSTRACT:
A coating composition of polymers of a vinyl oxazoline drying oil ester which esters are made by a process which reacts drying oil fatty acids with tris (hydroxy methyl) amino methane to form an intermediate which is further reacted at about 175.degree.-190.degree. C. with a formaldehyde/alcohol solution to form the vinyl oxazoline drying oil ester; the improvement used with this process is the use of at least 3 moles of formaldehyde to one mole of intermediate and about 1-5% by weight, based on the weight of the intermediate, of methanol and adding after the reaction with formaldehyde about 5-25% by weight, based on the weight of the ester solution, of an alcohol, a ketone or a mixture of an alcohol and a ketone; the coating composition are aqueous and contain sufficient ammonia or amine to provide a pH of about 7.5-9.5.

REFERENCES:
patent: 3248397 (1966-04-01), Purcell
patent: 3523123 (1970-08-01), Wehrmeister
patent: 3553124 (1971-01-01), Donatello et al.
patent: 3654229 (1972-04-01), Hunsucker
patent: 3960816 (1976-06-01), Jurisch
patent: 4147674 (1979-04-01), Vasta
Brochure Oxazolines by Commercial Solvents Corp., pp. 1-30, 1969.

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