Process for the preparation of tricyclo[5.3.1.0.sup.3,8 ]undecan

Chemistry of carbon compounds – Miscellaneous organic carbon compounds – C-metal

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260666M, 260617R, C07C 1354

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039767108

ABSTRACT:
A process for the preparation of tricyclo[5.3.1.0.sup.3,8 ]undecane which comprises isomerizing 5,6-exo-trimethylenenorbornyl-2-carbinol in the presence of an acid catalyst and a hydride donor.

REFERENCES:
krantz et al., Chem. Commun. 1971, 1287.
Krantz et al., J. Amer. Chem. Soc., 95, 5662, 1973.
Schleyer et al., Chem. Letters, 1189, 1973.
N. S. Vorobeva, O. A. Arefev, V. I. Epshev and A. A. Petrov, Chem. Ab., 75: 19562e, Neftekhimiya, 11, 163, 1971.
Naotake Takaishi et al., J. Org. Chem., 40, No. 3, pp. 276-281, 1975.

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