Process for preparing glyoxylic acid/aminomethylphosphonic acid

Chemistry: molecular biology and microbiology – Micro-organism – tissue cell culture or enzyme using process... – Preparing oxygen-containing organic compound

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435128, 435190, C12P 740, C12P 1300, C12N 904

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active

051358603

ABSTRACT:
The invention provides a process for producing mixtures of glyoxylic acid and aminomethylphosphonic acid. The process comprises reacting glycolic acid and oxygen in an aqueous solution in the presence of aminomethylphosphonic acid catalyst consisting of glycolate oxidase and catalase. The resulting mixtures are useful intermediates in the production of N-(phosphonomethyl)glycine.

REFERENCES:
patent: 4233452 (1980-11-01), Williams et al.
patent: 4455371 (1984-06-01), Richardson et al.
Tolbert et al. "J. Biol. Chem." vol. 181, pp. 905-914 (1949).
Zelitch et al, "J. Biol Chem." vol. 201, pp. 707-718 (1953).
Richardson et al. "J. Bio. Chem." vol. 178 pp. 977-987 (1949).

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