Process for the coproduction of alkyl iodides and alpha-iodocarb

Organic compounds -- part of the class 532-570 series – Organic compounds – Carboxylic acids and salts thereof

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562496, 562507, 562602, 562603, 562887, 562888, 570196, 570197, 570252, 570253, 570201, C07C 2700, C07C 5100

Patent

active

051440679

ABSTRACT:
Disclosed is a process for the coproduction of (1) an alkyl iodide and (2) an .alpha.-iodocarboxylic acid, a mono-.alpha.-iodocarboxylic anhydride or a mixture thereof which comprises contacting a mixture of an iodine compound and a carboxylic anhydride with a peroxide at an elevated temperature.

REFERENCES:
patent: 3647893 (1972-03-01), Silbert et al.
patent: 3652682 (1972-03-01), Silbert
patent: 3666820 (1972-05-01), Silbert
patent: 3716592 (1973-02-01), Silbert et al.
Silbert, et al, J. Org. Chem., 33, 3670 (1968).
Silbert, J. Am. Oil Chemists Soc., 46, 615 (1969).
Burger; Alfred: Medicinal Chemistry, 2nd Edition, p. 36, 1964.

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