Catalyst – solid sorbent – or support therefor: product or process – Catalyst or precursor therefor – Inorganic carbon containing
Patent
1996-01-23
1998-10-06
Bell, Mark L.
Catalyst, solid sorbent, or support therefor: product or process
Catalyst or precursor therefor
Inorganic carbon containing
502162, 502164, 502210, 502213, 502215, 502221, 502223, 502302, 502311, 502313, 502339, 502353, B01J 2118, B01J 27185, B01J 2342, B01J 2316
Patent
active
058175920
ABSTRACT:
A process for the preparation of a hydrogenation catalyst by reduction of platinum in an oxidation stage of not less than 2 in an aqueous medium in the presence of a carboniferous support, optionally following partial poisoning with a sulfur, arsenic, tellurium, or antimony-containing compound, using a reducing agent, in which the reducing agent used is an ammonium or phosphonium salt of the general formula I
in which X stands for N or P, R stands for hydrogen, C.sub.1 --C.sub.18 alkyl, C.sub.5 --C.sub.10 cycloalkyl, phenyl radical, and also a C.sub.1 --C.sub.4 alkyl radical substituted by phenyl, the phenyl radicals being mono-to tri-substituted by C.sub.1 --C.sub.6 alkyl, halogen, nitro or amino, if desired, provided that the radicals R may be the same or different but cannot simultaneously denote hydrogen, if X is P, n is an integer of 1 to 3, and Y is an organic anion which can reduce platinum in an oxidation stage other than zero to platinum in the oxidation stage of zero.
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Heineke Daniel
Schneider Heinz-Walter
Thome Alfred
BASF - Aktiengesellschaft
Bell Mark L.
Hailey Patricia L.
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