Process for preparing an oxime a structured catalyst including m

Organic compounds -- part of the class 532-570 series – Organic compounds – Amino nitrogen containing

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564253, C07C25144

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056377150

ABSTRACT:
A catalyst includes or consists essentially of the oxides of silicon, aluminum and titanium, characterized in that the catalyst particles are built up from a core with the composition (SiO.sub.2).sub.y (AlO.sub.2).sub.y M.sub.y, wherein x/y=10 to .infin. and M=H, Na, K, NH.sub.4, or NR.sub.4, wherein R is a C.sub.1-8 -alkyl, and a shell with the composition (SiO.sub.2).sub.n (TiO.sub.2).sub.m, wherein n/m=12 to 1000. Both the core and the shell have a crystal structure of MFI or MEL. The catalyst can be prepared by preparing a synthesis gel for the preparation of a titanium silicalite, thereafter introducing an aluminosilicata of the MFI or MEL structural type into this synthesis gel, and working up the synthesis gel in a known manner to obtain the product.

REFERENCES:
patent: 3535225 (1970-10-01), Jaffe
patent: 3702886 (1972-11-01), Argauer et al.
patent: 3709979 (1973-01-01), Chu
patent: 4061724 (1977-12-01), Grose et al.
patent: 4073865 (1978-02-01), Flanigen et al.
Meier, Walter M., Atlas of Zeolite Structure Types, 2nd Edition, 1987, pp. 586-587, 592-593.
Bibby, D.M., et al., "Silicalite-2, A Silica Analogue of the Aluminosilicate Zeolite ZSM-11", Nature, vol. 280, Aug. 23, 1979, pp. 664-665.
Sudhakar Reddy, J., et al., "Selective Oxidation of n-Hexane Over a Titanium Silicate Molecular Sieve with MEL Structure", Journal of Molecular Catalysis, 70 (1991), pp. 335-342.
Sudhakar Reddy, J., et al., "Ammoximation of Cyclohexanone Over a Titanium Silicate Molecular Sieve, TS-2", Journal of Molecular Catalysis, 69 (1991), pp. 383-392.
Clerici, Mario G., et al., "Epoxidation of Lower Olefins with Hydrogen Peroxide and Titanium Silicalite", Journal of Catalysis, 140 (1993), pp. 71-83.
Sudhakar Reddy, J., et al., "Titanium Silicate-2: Synthesis, Characterization and Catalytic Properties", Applied Catalysis, 58 (1990), pp. L1-L4.

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