Hydrogen sulfide removal and sulfide recovery

Chemistry of inorganic compounds – Sulfur or compound thereof – Elemental sulfur

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23293S, 23313FB, 55 69, 422189, 4235764, C01B 1705, B01D 500

Patent

active

049650629

ABSTRACT:
A process and apparatus for removing hydrogen sulfide from high pressure gas and recovering liquid sulfur, which includes reacting the H.sub.2 S with sulfite ions and an acetic acid-acid salt buffering system in an aqueous stream whereby liquid sulfur is formed, producing an effluent gas stream containing residual H.sub.2 S and an effluent aqueous stream containing the liquid sulfur, extracting the residual H.sub.2 S from the gaseous effluent stream, and using the extracted H.sub.2 S as well as H.sub.2 S recovered from the effluent aqueous stream as a source of sulfite ions for circulation to the reaction step, and as a source for additional liquid and solid sulfur. Apparatus and methods are also disclosed for recovering solid sulfur from a gaseous stream containing gaseous sulfur by contacting the gaseous stream with sulfur particles in a fluidized bed.

REFERENCES:
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Hampel et al., The Encyclopedia of Chemistry, 3rd ed., Van Nostrand Reinhold Co, 1973, pp. 166-167.
Kohl et al., Gas Purification, 3rd ed, Gulf Publishing Co, 1979, pp. 163-165.

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