Dehydrogenation method and multimetallic catalytic composite for

Chemistry of carbon compounds – Miscellaneous organic carbon compounds – C-metal

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2606833, 208138, 252439, 252466PT, C07C 1500, C07C 328, C07C 532

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active

039325482

ABSTRACT:
Dehydrogenatable hydrocarbons are dehydrogenated by contacting them, at dehydrogenation conditions, with a catalytic composite comprising a combination of catalytically effective amounts of a platinum group component, a Group IB transition metal component, a rhenium component and a tin component with a porous carrier material. A specific example of the catalytic composite disclosed herein is a combination of a platinum group component, a Group IB component, a rhenium component, a tin component and an alkali or alkaline earth component with a porous carrier material wherein substantially all of the platinum group component, the Group IB component and the rhenium component are present as the corresponding elemental metals and substantially all of the tin component is present in an oxidation state above the elemental metal, and wherein the composite contains about 0.01 to about 2 wt. % platinum group metal, about 0.01 to about 5 wt. % Group IB metal, about 0.01 to about 2 wt. % rhenium, about 0.01 to about 5 wt. % tin and about 0.01 to about 5 wt. % alkali or alkaline earth metal.

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