Radiation and peroxide curable emulsified coatings

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – Compositions to be polymerized by wave energy wherein said...

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522100, 522104, 522114, 523406, 523501, 523526, 524507, 524517, 524558, 526230, 5262321, 526333, 526109, C08F 246, C08F 442, C08F 1612

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053691393

ABSTRACT:
Radiation and peroxide-curable oligomeric emulsions are prepared by mixing water, an .alpha.,.beta.-ethylenically unsaturated oligomer (e.g. an unsaturated polyester), a reactive, nonionic surfactant containing allyl unsaturation, and a metallic salt drier under high shear agitation until a stable emulsion is formed. Coatings prepared from these emulsions are tack and mar free and demonstrate good resistance to organic solvents and water.

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Davis, et al., The Synthesis and Properties of a Novel Series of Water Soluble Thioxanthone Photoinitiators, 1986, pp. 9-12, Chemspec '86 BACS Symposium.
Philips, et al., Radiationcurable Water Dilutable Polyesteracrylates, pp. 157-161, Drogenbos, Belgium.
Allen, et al., Photochemistry of Novel Water-Soluble Parasubstituted Benzophenone Photoinitiators: A Photocalorimetric and Photoreduction Study, 1988, pp. 171-177, Journal of Photochemistry and Photobiology.
P-CURE Resins for Peroxide-Curable Coatings, Cook Composite and Polymers, Freeman Polymer Division.
Beck, et al., Radiation Curing and Water, Mar. 1992, Farbe+Lack.

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