Organoaluminoxy product, preparation, and use

Catalyst – solid sorbent – or support therefor: product or process – Catalyst or precursor therefor – Plural component system comprising a - group i to iv metal...

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502103, 502117, 556175, 556179, 556183, 526138, 526142, 526160, C08F 402, C08F 462, C08F 464

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active

054362121

ABSTRACT:
In accordance with the present invention, there is provided a solid organoaluminoxy product prepared by reacting an organoaluminoxane with an oxygen-containing compound selected from the group consisting of organic peroxide, alkylene oxide, or organic carbonate. Further there is provided olefin polymerization catalyst systems comprising the solid organoaluminoxy product and a transition metal-containing catalyst. Still further there is provided processes for the polymerization of olefins using the catalyst systems.

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"Ethylaluminum Oxide Catalysts form Et.sub.3 AlOi-Et.sub.2 AlCl Binary System in Relation to Species of AlEt.sub.3 -Water Catalyst", Takeo Araki et al., Journal of Polymer Science, vol. 11, pp. 699-712, 1973.
"Behavior of the R.sub.2 AlOAlR.sub.2 Catalyst in the Polymerization of Propylene Oxide", Ueyama et al., Macromoecules, vol. 7, No. 2, Mar.-Apr. 1974, pp. 153-160.
"Polymethylaluminum Oxide and Stereoregular Polymerization of Propylene Oxide", Oktem et al., Eur. Polymer J., Vol. 29, No. 5, pp. 637-643, 1993.

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