Process for the production of o-aminophenyl ketone derivatives

Details Process for the production of o-aminophenyl ketone derivatives Process for the production of o-aminophenyl ketone derivatives

1977-02-18

1979-07-10

Hines, Robert V.

Chemistry of carbon compounds

Miscellaneous organic carbon compounds

C-metal

260551B, 260566R, 2605705P, 260575, 260577, 260578, C07C 8518

Patent

active

041607848

ABSTRACT:
O-Aminophenyl ketone derivatives are regio-specifically prepared by reacting an aniline unsubstituted in at least one ortho position with a nitrile in the presence of boron trihalogenide to introduce a substituted iminomethyl into the ortho position of said aniline and hydrolyzing the resulting iminomethyl compound.

REFERENCES:
olah, "Friedel-Crafts and Related Reactions", vol. III, Part I, pp. 394-408 (1964).
Olah (II), "Friedel-Crafts and Related Reactions", vol. I, pp. 517-518 (1963).
Sidgwicke, "The Organic Chemistry of Nitrogen", p. 446 (1966), 3rd Ed.

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