Substitutive fluorination of organic compounds

Chemistry: electrical and wave energy – Processes and products – Processes of treating materials by wave energy

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204158HA, 204158HE, 20415913, 20415914, 20415918, 20415919, 20415920, 204163R, 204163HE, 260534R, 260534C, 260648F, 260649F, 260653, 2606531R, 2606531T, 2606534, 526 21, 526 22, 526 41, 526 46, 528483, 528487, 528491, 528494, C08F 246, C08F 254, C08F 800

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040309940

ABSTRACT:
Organic compounds having at least one replaceable hydrogen atom are fluorinated in the liquid or solid state by treatment with fluoroxyperfluoroalkanes or fluoroxypentafluorosulfur under the influence of a free radical initiator.

REFERENCES:
patent: 3081243 (1963-03-01), Feng
patent: 3104214 (1963-09-01), D'Alelio
patent: 3151051 (1964-09-01), Braid et al.
patent: 3456024 (1969-07-01), Loree
Cady, Proc. Chem. Soc., 133-138 (1960).
Allison et al., Abstract 63, A.C.S. Meeting, Chicago (1968).
Sheppard et al., Organic Fluorine Chemistry p. 231 (Benjamin, New York, N.Y. 1969).
Florocarbon and Related Chemistry, vol. I, (1971), Banks and Barlow p. 153.

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